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oxalyl chloride : ウィキペディア英語版
oxalyl chloride

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Oxalyl chloride is a chemical compound with the formula (COCl)2. This colourless, sharp-smelling liquid, the diacid chloride of oxalic acid, is a useful reagent in organic synthesis. It can be prepared by treating oxalic acid with phosphorus pentachloride.
==Reactions==
Oxalyl chloride reacts with water giving off gaseous products only: hydrogen chloride (HCl), carbon dioxide (), and carbon monoxide (CO). In this, it is quite different from other acyl chlorides which hydrolyze with formation of hydrogen chloride and the original carboxylic acid.
: + → 2 + +

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